ASTM D4929-04
Standard Test Methods for Determination of Organic Chloride Content in Crude Oil

Standard No.
ASTM D4929-04
Release Date
2004
Published By
American Society for Testing and Materials (ASTM)
Status
Replace By
ASTM D4929-07
Latest
ASTM D4929-22
Scope

Organic chloride species are potentially damaging to refinery processes. Hydrochloric acid can be produced in hydrotreating or reforming reactors and the acid accumulates in condensing regions of the refinery. Unexpected concentrations of organic chlorides cannot be effectively neutralized and damage can result. Organic chlorides are not known to be naturally present in crude oils and usually result from cleaning operations at producing sites, pipelines, or tanks. It is important for the oil industry to have common methods available for the determination of organic chlorides in crude oil, particularly when transfer of custody is involved.

1.1 These test methods cover the determination of organic chloride (above 1 g/g organically-bound chlorine) in crude oils, using either distillation and sodium biphenyl reduction or distillation and microcoulometry.

1.2 These test methods involve the distillation of crude oil test specimens to obtain a naphtha fraction prior to chloride determination. The chloride content of the naphtha fraction of the whole crude oil can thereby be obtained. See Section regarding potential interferences.

1.3 Test Method A covers the determination of organic chloride in the washed naphtha fraction of crude oil by sodium biphenyl reduction followed by potentiometric titration.

1.4 Test Method B covers the determination of organic chloride in the washed naphtha fraction of crude oil by oxidative combustion followed by microcoulometric titration.

1.5 Values expressed in acceptable SI units are to regarded as the standard. The preferred concentration units are micrograms of chloride per gram of sample.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ASTM D4929-04 history

  • 2022 ASTM D4929-22 Standard Test Method for Determination of Organic Chloride Content in Crude Oil
  • 2019 ASTM D4929-19a Standard Test Method for Determination of Organic Chloride Content in Crude Oil
  • 2019 ASTM D4929-19 Standard Test Method for Determination of Organic Chloride Content in Crude Oil
  • 2017 ASTM D4929-17 Standard Test Method for Determination of Organic Chloride Content in Crude Oil
  • 2016 ASTM D4929-16 Standard Test Method for Determination of Organic Chloride Content in Crude Oil
  • 2015 ASTM D4929-15a Standard Test Methods for Determination of Organic Chloride Content in Crude Oil
  • 2015 ASTM D4929-15 Standard Test Methods for Determination of Organic Chloride Content in Crude Oil
  • 2007 ASTM D4929-07(2014) Standard Test Methods for Determination of Organic Chloride Content in Crude Oil
  • 2007 ASTM D4929-07 Standard Test Methods for Determination of Organic Chloride Content in Crude Oil
  • 2004 ASTM D4929-04 Standard Test Methods for Determination of Organic Chloride Content in Crude Oil
  • 1999 ASTM D4929-99e1 Standard Test Methods for Determination of Organic Chloride Content in Crude Oil
  • 1999 ASTM D4929-99 Standard Test Methods for Determination of Organic Chloride Content in Crude Oil



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