ASTM D5315-04(2017)e1
Standard Test Method for Determination of N-Methyl-Carbamoyloximes and N-Methylcarbamates in Water by Direct Aqueous Injection HPLC with Post-Column Derivatization

Standard No.
ASTM D5315-04(2017)e1
Release Date
2004
Published By
American Society for Testing and Materials (ASTM)
Latest
ASTM D5315-04(2017)e1
Scope

5.1 N-methylcarbamates and n-methylcarbomoyloximes are used in agriculture as insecticides and herbicides. They are sometimes found in both surface and ground waters and can be toxic to animals and plants at moderate to high concentrations. The manufacturing precursors and degradation products may be equally as hazardous to the environment.

1.1 This is a high-performance liquid chromatographic (HPLC) test method applicable to the determination of certain n-methylcarbamoyloximes and n-methylcarbamates in ground water and finished drinking water (1).2 This test method is applicable to any carbamate analyte that can be hydrolyzed to a primary amine. The following compounds have been validated using this test method:

Analyte

Chemical Abstract Services
Registry Number8201;A

8199;8199;8199;Aldicarb

8199;8199;8199;8199;8199;8199;116-06-3

8199;8199;8199;Aldicarb sulfone

8199;8199;8199;8199;8199;8199;1646-88-4

8199;8199;8199;Aldicarb sulfoxide

8199;8199;8199;8199;8199;8199;1646-87-3

8199;8199;8199;Baygon

8199;8199;8199;8199;8199;8199;114-26-1

8199;8199;8199;Carbaryl

8199;8199;8199;8199;8199;8199;63-25-2

8199;8199;8199;Carbofuran

8199;8199;8199;8199;8199;8199;1563-66-2

8199;8199;8199;3-Hydroxycarbofuran

8199;8199;8199;8199;8199;8199;16655-82-6

8199;8199;8199;Methiocarb

8199;8199;8199;8199;8199;8199;2032-65-7

8199;8199;8199;Methomyl