ASTM D6784-16
Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method)

Standard No.

ASTM D6784-16

Release Date

2016

Published By

American Society for Testing and Materials (ASTM)

Status

Be replaced

Replace By

ASTM D6784-24

Latest

ASTM D6784-24

Scope

5.1 The measurement of particle-bound, oxidized, elemental, and total mercury in stationary-source flue gases provides data that can be used for emissions assessments and reporting, the certification of continuous mercury monitoring systems, regulatory compliance determinations and research programs associated with dispersion modeling, deposition evaluation, human health and environmental impact assessments. Particle-bound, oxidized, and elemental mercury measurements before and after control devices may be necessary for optimizing and evaluating the mercury removal efficiency of emission control technologies.

5.2 This test method was developed for the measurement of mercury in coal-fired power plants and has been extensively validated for that application. With additional procedures given in this standard, it is also applicable to sources having a flue gas composition with high levels of hydrochloric acid, and low levels of sulfur dioxide.

1.1 This test method applies to the determination of elemental, oxidized, particle-bound, and total mercury emissions from coal-fired stationary sources.

1.2 This test method is applicable to elemental, oxidized, particle-bound, and total mercury concentrations ranging from approximately 0.5 to 100 μg/Nm³.

1.3 This test method describes equipment and procedures for obtaining samples from effluent ducts and stacks, equipment and procedures for laboratory analysis, and procedures for calculating results.

1.4 This test method is applicable for sampling elemental, oxidized, and particle-bound mercury in flue gases of coal-fired stationary sources. It may not be suitable at all measurement locations, particularly those with high particulate loadings, as explained in Section 16.

1.5 Method applicability is limited to flue gas stream temperatures within the thermal stability range of the sampling probe and filter components.

1.6 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.

1.7 This standard requires users to be familiar with EPA stack-gas sampling procedures as stated in EPA Methods 1–4, Method 5, and Method 17.

1.8 The method requires a high level of experience and quality control both in the field testing and analytical procedures in order to obtain high quality data.

1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ASTM D6784-16 Referenced Document

• ASTM D1193 Standard Specification for Reagent Water
• ASTM D1356 Standard Terminology Relating to Sampling and Analysis of Atmospheres*， 2024-04-20 Update
• ASTM D3154 Standard Test Method for Average Velocity in a Duct (Pitot Tube Method)
• ASTM D3685/D3685M Standard Test Methods for Sampling and Determination of Particulate Matter in Stack Gases
• ASTM D3796 Standard Practice for Calibration of Type S Pitot Tubes
• ASTM D4840 Standard Guide for Sample Chain-of-Custody Procedures
• ASTM D7036 Standard Practice for Competence of Air Emission Testing Bodies
• ASTM E2251 Standard Specification for Liquid-in-Glass ASTM Thermometers with Low-Hazard Precision Liquids

ASTM D6784-16 history

• 2024 ASTM D6784-24 Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method)
• 2016 ASTM D6784-16 Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method)
• 2002 ASTM D6784-02(2008) Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method)
• 2002 ASTM D6784-02 Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method)