ASTM F2625-10(2016) PDF

Scope: 5.1 The crystallinity of UHMWPE will influence its mechanical properties, such as creep and stiffness. The reported crystallinity will depend on the integration range used to determine the heat of fusion, and the theoretical heat of fusion of 1008201;% crystalline polyethylene used to calculate the percent crystallinity in an unknown specimen. Differential scanning calorimetry is an effective means of accurately measuring both heat of fusion and melting temperature.

5.2 This test method is useful for both process control and research.

1.1 This test method discusses the measurement of the heat of fusion and the melting point of ultra-high-molecular weight polyethylene (UHMWPE), and the subsequent calculation of the percentage of crystallinity.

1.2 This test method can be used for UHMWPE in powder form, consolidated form, finished product, or a used product. It can also be used for irradiated or chemically-crosslinked UHMWPE.

1.3 This test method does not suggest a desired range of crystallinity or melting points for specific applications.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ASTM F2625-10(2016) Referenced Document

ASTM D3418 Standard Test Method for Transition Temperatures of Polymers By Differential Scanning Calorimetry
ASTM E1953 Standard Practice for Description of Thermal Analysis Apparatus
ASTM E691 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM E793 Standard Test Method for Enthalpies of Fusion and Crystallization by Differential Scanning Calorimetry
ASTM E967 Standard Practice for Temperature Calibration of Differential Scanning Calorimeters and Differential Thermal Analyzers
ASTM E968 Standard Practice for Heat Flow Calibration of Differential Scanning Calorimeters

2010 ASTM F2625-10(2016) Standard Test Method for Measurement of Enthalpy of Fusion, Percent Crystallinity, and Melting Point of Ultra-High-Molecular Weight Polyethylene by Means of Differential Scanning Calorimetry
2010 ASTM F2625-10 Standard Test Method for Measurement of Enthalpy of Fusion, Percent Crystallinity, and Melting Point of Ultra-High-Molecular Weight Polyethylene by Means of Differential Scanning Calorimetry
2007 ASTM F2625-07 Standard Test Method for Measurement of Enthalpy of Fusion, Percent Crystallinity, and Melting Point of Ultra-High-Molecular Weight Polyethylene by Means of Differential Scanning Calorimetry