ASTM D7542-15
Standard Test Method for Air Oxidation of Carbon and Graphite in the Kinetic Regime

Standard No.

ASTM D7542-15

Release Date

2015

Published By

American Society for Testing and Materials (ASTM)

Status

Be replaced

Replace By

ASTM D7542-21

Latest

ASTM D7542-21

Scope

5.1 This test method can be used to measure the rate of oxidation for various grades of manufactured carbon and graphite in standard conditions, and can be used for quality control purposes.

5.2 The following conditions are standardized in this test method: size and shape of the graphite specimens; their placement in the vertical furnace with upwards air flow; the method for continuous weight variation measurement using an analytical scale with under-the-scale port; the air flow rate, which is high enough to ensure that oxidation is not oxygen-starved at the highest temperature used; the initial and final points on the weight loss curve used for calculation of oxidation rate.

5.3 This test method also provides kinetic parameters (activation energy and logarithm of pre-exponential factor) for the oxidation reaction, and a standard oxidation temperature. The results uniquely characterize the effect of temperature on oxidation rates in air, and the oxidation resistance of machined carbon or graphite specimens with standard size and shape, in the kinetic, or chemically controlled, oxidation regime. This information is useful for discrimination between material grades with different impurity levels, grain size, pore structure, degree of graphitization, or antioxidation treatments, or a combination thereof.

5.4 Accurately determined kinetic parameters, like activation energy and logarithm of pre-exponential factor, can be used for prediction of oxidation rates in air as a function of temperature in conditions similar to those of this test method. However, extrapolation of such predictions outside the temperature range where Arrhenius plots are linear (outside the kinetic or chemically controlled regime of oxidation) should be made with extreme caution. In conditions where oxidation rates become controlled by a mechanism other than chemical reactions, such as in-pore diffusion or boundary transport of the oxidant gas, prediction of oxidation rates using kinetic parameters determined with this test method will produce overestimated results.

1.1 This test method recommends a standard procedure for measuring oxidation rates in air of various grades of nuclear graphite and/or manufactured carbon. Following the standard procedure recommended here, one can obtain kinetic parameters that characterize the oxidation resistance of tested materials and that can be used to for materials selection and qualification, and for quality control purposes in the fabrication process.

1.2 This test method covers the rate of oxidative weight loss per exposed nominal geometric surface area, or per initial weight of machined test specimens of standard size and shape, or both. The test is valid in the temperature range where the rate of air oxidation of graphite and manufactured carbon is limited by reaction kinetics.

1.3 This test method also provides a standard oxidation temperature (as defined in 3.1.7), and the kinetic parameters of the oxidation reaction, namely the activation energy and the logarithm of pre-exponential factor in Arrhenius equation. The kinetic parameters of Arrhenius equation are calculated from the temperature dependence of oxidation rates measured over the temperature range where Arrhenius plots (a......

ASTM D7542-15 Referenced Document

• ASTM C559 Standard Test Method for Bulk Density by Physical Measurements of Manufactured Carbon and Graphite Articles
• ASTM E1582 Standard Practice for Calibration of Temperature Scale for Thermogravimetry
• ASTM E1970 Standard Practice for Statistical Treatment of Thermoanalytical Data
• ASTM E691 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
• ASTM E898 Standard Test Method of Testing Top-Loading, Direct-Reading Laboratory Scales and Balances

ASTM D7542-15 history

• 2021 ASTM D7542-21 Standard Test Method for Air Oxidation of Carbon and Graphite in the Kinetic Regime
• 2015 ASTM D7542-15 Standard Test Method for Air Oxidation of Carbon and Graphite in the Kinetic Regime
• 2009 ASTM D7542-09 Standard Test Method for Air Oxidation of Carbon and Graphite in the Kinetic Regime