5.1 Sulfur dioxide is a major air pollutant, commonly formed by the combustion of sulfur-bearing fuels. The Environmental Protection Agency (EPA) has set primary and secondary air quality standards (7) that are designed to protect the public health and welfare.
5.2 The Occupational Safety and Health Administration (OSHA) has promulgated exposure limits for sulfur dioxide in workplace atmospheres (8).
5.3 These methods have been found satisfactory for measuring sulfur dioxide in ambient and workplace atmospheres over the ranges pertinent in 5.1 and 5.2.
5.4 Method A has been designed to correspond to the EPA-Designated Reference Method (7) for the determination of sulfur dioxide.
1.1 These test methods cover the bubbler collection and colorimetric determination of sulfur dioxide (SO2) in the ambient or workplace atmosphere.
1.2 These test methods are applicable for determining SO2 over the range from approximately 25 μg/m3 (0.01 ppm(v)) to 1000 μg/m3 (0.4 ppm(v)), corresponding to a solution concentration of 0.03 μg SO2/mL to 1.3 μg SO2/mL. Beer's law is followed through the working analytical range from 0.02 μg SO2/mL to 1.4 μg SO2/mL.
1.3 The lower limit of detection is 0.075 μg SO2/mL (1),2 representing an air concentration of 25 μg SO2/m3 (0.01 ppm(v)) in a 30–min sample, or 13 μg SO2/m3 (0.005 ppm(v)) in a 24–h sample.
ASTM D2914-15 Referenced Document
ASTM D2914-15 history
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