ASTM E1640-13
Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis

Standard No.

ASTM E1640-13

Release Date

2013

Published By

American Society for Testing and Materials (ASTM)

Status

Be replaced

Replace By

ASTM E1640-13(2018)

Latest

ASTM E1640-23

Scope

5.1 This test method can be used to locate the glass transition region and assign a glass transition temperature of amorphous and semi-crystalline materials.

5.2 Dynamic mechanical analyzers monitor changes in the viscoelastic properties of a material as a function of temperature and frequency, providing a means to quantify these changes. In ideal cases, the temperature of the onset of the decrease in storage modulus marks the glass transition.

5.3 A glass transition temperature (T_g) is useful in characterizing many important physical attributes of thermoplastic, thermosets, and semi-crystalline materials including their thermal history, processing conditions, physical stability, progress of chemical reactions, degree of cure, and both mechanical and electrical behavior. T_g may be determined by a variety of techniques and may vary in accordance with the technique.

5.4 This test method is useful for quality control, specification acceptance, and research.

1.1 This test method covers the assignment of a glass transition temperature (T_g) of materials using dynamic mechanical analyzers.

1.2 This test method is applicable to thermoplastic polymers, thermoset polymers, and partially crystalline materials which are thermally stable in the glass transition region.

1.3 The applicable range of temperatures for this test method is dependent upon the instrumentation used, but, in order to encompass all materials, the minimum temperature should be about8201;−150°C.

1.4 This test method is intended for materials having an elastic modulus in the range of 0.5 MPa to 100 GPa.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard is similar to IEC 61006 except that standard uses the peak temperature of the loss modulus peak as the glass transition temperature while this standard uses the extrapolated onset temperature of the storage modulus change.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ASTM E1640-13 Referenced Document

• ASTM D4092 Standard Terminology: Plastics: Dynamic Mechanical Properties
• ASTM E1142 Standard Terminology Relating to Thermophysical Properties
• ASTM E1363 Standard Test Method for Temperature Calibration of Thermomechanical Analyzers
• ASTM E1545 Standard Test Method for Assignment of the Glass Transition Temperature by Thermomechanical Analysis
• ASTM E1867 Standard Test Method for Temperature Calibration of Dynamic Mechanical Analyzers
• ASTM E2254 Standard Test Method for Storage Modulus Calibration of Dynamic Mechanical Analyzers
• ASTM E2425 Standard Test Method for Loss Modulus Conformance of Dynamic Mechanical Analyzers
• ASTM E691 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

ASTM E1640-13 history

• 2023 ASTM E1640-23 Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis
• 2018 ASTM E1640-18 Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis
• 2018 ASTM E1640-13(2018) Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis
• 2013 ASTM E1640-13 Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis
• 2009 ASTM E1640-09 Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis
• 2004 ASTM E1640-04 Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis
• 1999 ASTM E1640-99 Standard Test Method for Assignment of the Glass Transition Temperature By Dynamic Mechanical Analysis