ASTM D3452-06(2012)
Standard Practice for Rubbermdash;Identification by Pyrolysis-Gas Chromatography

Standard No.

ASTM D3452-06(2012)

Release Date

2006

Published By

American Society for Testing and Materials (ASTM)

Status

Be replaced

Replace By

ASTM D3452-06(2017)

Latest

ASTM D3452-06(2021)

Scope

3.1 For research, development, and quality control purposes, it is advantageous to determine the composition of rubbers in cured, compounded products.

3.2 This practice provides such composition analysis, utilizing a gas chromatograph and pyrolysis products from rubber decomposition.

1.1 This practice covers the identification of polymers in raw rubbers, and cured and uncured compounds, based on a single polymer, by the gas chromatographic patterns of their pyrolysis products (pyrograms). Implementation of this guide presupposes a working knowledge of the principles and techniques of gas chromatography, sufficient to carry out this practice and to interpret the results correctly.²

1.2 This practice will identify the following polymers:

1.2.1 Polyisoprene of natural or synthetic origin,

1.2.2 Butadiene-styrene copolymers,

1.2.3 Polybutadiene,

1.2.4 Polychloroprene,

1.2.5 Butadiene-acrylonitrile copolymers,

1.2.6 Ethylene-propylene copolymers and related terpolymers, and

1.2.7 Isobutene-isoprene copolymers.

1.3 This practice will not differentiate the following polymers:

1.3.1 Natural polyisoprene from synthetic polyisoprene.

1.3.2 Butadiene-styrene copolymers produced by solution and emulsion polymerization. It is sometimes possible to distinguish butadiene-styrene copolymers containing different amounts of styrene as well as random polymers from block polymers.

1.3.3 Polybutadiene with different microstructures.

1.3.4 Different types of polychloroprenes.

1.3.5 Butadiene-acrylonitrile copolymers with different monomer ratios.

1.3.6 Ethylene-propylene copolymers with different monomer ratios, as well as the copolymers from the related terpolymers.

1.3.7 Isobutene-isoprene copolymers (butyl rubbers) from halogenated butyl rubbers.

1.3.8 Polyisoprene containing different amounts of cis-trans isomers.

1.3.9 The practice does not identify ebonite or hard rubbers.

1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.

ASTM D3452-06(2012) Referenced Document

• ASTM D297 Standard Test Methods for Rubber Products-Chemical Analysis
• ASTM E260 Standard Practice for Packed Column Gas Chromatography
• ASTM E355 Standard Practice for Gas Chromatography Terms and Relationships*， 2024-04-20 Update

ASTM D3452-06(2012) history

• 2021 ASTM D3452-06(2021) Standard Practice for Rubber—Identification by Pyrolysis-Gas Chromatography
• 2017 ASTM D3452-06(2017) Standard Practice for Rubber Identification by Pyrolysis Gas Chromatography
• 2006 ASTM D3452-06(2012) Standard Practice for Rubbermdash;Identification by Pyrolysis-Gas Chromatography
• 2006 ASTM D3452-06 Standard Practice for Rubber—Identification by Pyrolysis-Gas Chromatography
• 1993 ASTM D3452-93(2002) Standard Practice for Rubber8212;Identification by Pyrolysis-Gas Chromatography
• 1998 ASTM D3452-93(1998) Standard Practice for Rubber-Identification by Pyrolysis-Gas Chromatography