ASTM D1688-12
Standard Test Methods for Copper in Water

Standard No.
ASTM D1688-12
Release Date
2012
Published By
American Society for Testing and Materials (ASTM)
Status
Replace By
ASTM D1688-17
Latest
ASTM D1688-17
Scope

4.1 Copper is found in naturally occurring minerals principally as a sulfide, oxide, or carbonate. It makes up approximately 0.018201;% of the earth's crust and is obtained commercially from such ores as chalcopyrite (CuFeS2). Copper is also found in biological complexes such as hemocyanin.

4.2 Copper enters water supplies through the natural process of dissolution of minerals, through industrial effluents, through its use, as copper sulfate, to control biological growth in some reservoirs and distribution systems, and through corrosion of copper alloy water pipes. Industries whose wastewaters may contain significant concentrations of copper include mining, ammunition production, and most metal plating and finishing operations. It may occur in simple ionic form or in one of many complexes with such groups as cyanide, chloride, ammonia, or organic ligands.

4.3 Although its salts, particularly copper sulfate, inhibit biological growth such as some algae and bacteria, copper is considered essential to human nutrition and is not considered a toxic chemical at concentrations normally found in water supplies.

1.1 These test methods cover the determination of copper in water by atomic absorption spectrophotometry. Three test methods are included as follows:

Test Method

Concentration
Range

8201;
Sections

A—Atomic Absorption, Direct

0.05 to 5 mg/L

8199;7-15

B—Atomic Absorption, Chelation-Extraction

50 to 500 μg/L

16-......

ASTM D1688-12 Referenced Document

  • ASTM D1066 Standard Practice for Sampling Steam
  • ASTM D1068 Standard Test Methods for Iron in Water
  • ASTM D1129 Standard Terminology Relating to Water
  • ASTM D1193 Standard Specification for Reagent Water
  • ASTM D1687 Standard Test Methods for Chromium in Water
  • ASTM D1691 Standard Test Methods for Zinc in Water
  • ASTM D1886 Standard Test Methods for Nickel in Water
  • ASTM D2777 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
  • ASTM D3370 Standard Practices for Sampling Water from Closed Conduits
  • ASTM D3557 Standard Test Methods for Cadmium in Water
  • ASTM D3558 Standard Test Methods for Cobalt in Water
  • ASTM D3559 Standard Test Methods for Lead in Water
  • ASTM D3919 Standard Practice for Measuring Trace Elements in Water by Graphite Furnace Atomic Absorption Spectrophotometry
  • ASTM D4841 Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
  • ASTM D5810 Standard Guide for Spiking into Aqueous Samples 
  • ASTM D5847 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
  • ASTM D858 Standard Test Methods for Manganese in Water

ASTM D1688-12 history

Standard Test Methods for  Copper in Water



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