ASTM D7828-12
Standard Test Method for Determination of Residue Composition in Liquefied Petroleum Gas (LPG) Using Automated Thermal Desorption/Gas Chromatography (ATD/GC)

Standard No.

ASTM D7828-12

Release Date

2012

Published By

American Society for Testing and Materials (ASTM)

Latest

ASTM D7828-12

Scope

5.1 Residue in LPG is a contaminant that can lead to operational problems in some end use applications. Engines, micro-turbines, fuel cells and other equipment may be sensitive to residue levels as low as 10 mg/kg.

5.2 Contamination of LPG can occur during production, transport, delivery, storage and use. A qualitative indication of the contaminants can help track down the source of the contamination from manufacture, through the distribution system, and to the end user.

5.3 This test method is designed to provide a lower detection limit, wider dynamic range, and better accuracy than gravimetric methods like Test Method D2158.

5.4 This test method can be performed with little or no discharge of LPG vapors, compared to Test Method D2158 which requires evaporation of 100 mL of sample per test.

5.5 Sampling for residue in LPG using sorbent tubes can be performed in the field, and the sorbent tubes sent to a laboratory for analysis. This saves significant costs in shipping (weight of tube is approximately 10 grams), and is much safer and easier than transporting LPG cylinders.

5.6 This test method determines total residues from C₆ to C₄₀, compared to a thermal gravimetric residue method such as Test Method D2158 which heat the residue to 38°C, resulting in a lower recovery due to loss of lighter residue components.

5.7 If there is a need to decrease the detection limit of residue or individual compounds of interest below 10 µg/g, the procedures in this test method can be modified to achieve 50 times enhanced detection limit, or 0.2 µg/g.

1.1 This test method covers the determination of residue in LPG by automated thermal desorption/gas chromatography (ATD/GC) using flame ionization detection (FID).

1.2 The quantitation of residue covers a component boiling point range from 69°C to 522°C, equivalent to the boiling points of C₆ through C₄₀ n-paraffins.

1.2.1 The boiling range covers possible LPG contaminants such as gasoline, diesel fuel, phthalates and compressor oil. Qualitative information on the nature of the residue can be obtained from this test method.

1.2.2 Materials insoluble in LPG and components which do not elute from the gas chromatograph or which have no response in a flame ionization detector are not determined.

1.2.3 The reporting limit (or limit of quantitation) for total residue is 6.7 µg/g.

1.2.4 The dynamic ......

ASTM D7828-12 Referenced Document

• ASTM D1265 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
• ASTM D1835 Standard Specification for Liquefied Petroleum (LP) Gases
• ASTM D2158 Standard Test Method for Residues in Liquefied Petroleum (LP) Gases
• ASTM D3700 Standard Practice for Obtaining LPG Samples Using a Floating Piston Cylinder
• ASTM D6299 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
• ASTM E355 Standard Practice for Gas Chromatography Terms and Relationships*， 2024-04-20 Update

ASTM D7828-12 history

• 2012 ASTM D7828-12 Standard Test Method for Determination of Residue Composition in Liquefied Petroleum Gas (LPG) Using Automated Thermal Desorption/Gas Chromatography (ATD/GC)