1.14 MPa (150 psig) will generally elevate the boiling point of a volatile organic substance 100??C. Under these conditions exothermic decomposition is often observed.
5.4 For some substances the rate of enthalpy change during an exothermic reaction may be small at normal atmospheric pressure, making an assessment of the temperature of instability difficult. Generally a repeated analysis at an elevated pressure will improve the assessment by increasing the rate of change of enthalpy.
Note 1???The choice of pressure may sometimes be estimated by the pressure of the application to which the material is exposed.
5.5 The four significant criteria of this test method are: the detection of a change of enthalpy; the approximate temperature at which the event occurs; the estimation of its enthalpy and the observance of effects due to the cell atmosphere and pressure.
1.1 This test method describes the ascertainment of the presence of enthalpic changes in a test specimen, using minimum quantities of material, approximates the temperature at which these enthalpic changes occur and determines their enthalpies (heats) using differential scanning calorimetry or pressure differential scanning calorimetry.
1.2 This test method may be performed on solids, liquids, or slurries.
1.3 This test method may be performed in an inert or a reactive atmosphere with an absolute pressure range from 100 Pa through 7 MPa and over a temperature range from 300 to 800 K (27 to......
ASTM E537-12 Referenced Document
ASTM E1445 Standard Terminology Relating to Hazardous Potential of Chemicals
ASTM E1860 Standard Test Method for Elapsed Time Calibration Thermal Analyzers
ASTM E473 Standard Terminology Relating to Thermal Analysis
ASTM E691 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM E967 Standard Practice for Temperature Calibration of Differential Scanning Calorimeters and Differential Thermal Analyzers
ASTM E968 Standard Practice for Heat Flow Calibration of Differential Scanning Calorimeters
ASTM E537-12 history
2020ASTM E537-20 Standard Test Method for Thermal Stability of Chemicals by Differential Scanning Calorimetry
2012ASTM E537-12 Standard Test Method for The Thermal Stability of Chemicals by Differential Scanning Calorimetry
2007ASTM E537-07 Standard Test Method for The Thermal Stability Of Chemicals By Differential Scanning Calorimetry
2002ASTM E537-02 Standard Test Method for The Thermal Stability Of Chemicals By Differential Scanning Calorimetry
1998ASTM E537-98 Standard Test Method for Assessing the Thermal Stability of Chemicals By Methods of Thermal Analysis