1.1 This test method is intended to quantitatively determine the non-condensed hydrocarbon gases with carbon numbers from C1 to C5+ and non-hydrocarbon gases, such as H2, CO2, O2, N2, and CO, in gaseous samples. This test method is a companion standard test method to Test Method D1945 and Practice D1946 differing in that it incorporates use of capillary columns instead of packed columns and allows other technological differences.
1.2 Hydrogen sulfide can be detected but may not be accurately determined by this procedure due to loss in sample containers or sample lines and possible reactions unless special precautions are taken.
1.3 Non-hydrocarbon gases have a lower detection limit in the concentration range of 0.03 to 100 mole percent using a thermal conductivity detector (TCD) and C1 to C6 hydrocarbons have a lower detection limit in the range of 0.005 to 100 mole percent using a flame ionization detector (FID); using a TCD may increase the lower detection limit to approximately 0.03 mole percent.
1.3.1 Hydrocarbon detection limits can be reduced with the use of pre-concentration techniques and/or cryogenic trapping.
1.4 This test method does not fully determine individual hydrocarbons heavier than benzene, which are grouped together as C7+ When detailed analysis is not required the compounds with carbon number greater than C5 may be grouped as either C6+, or C7+. Accurate analysis of C
ASTM D7833-12 Referenced Document
ASTM D1945 Standard Test Method for Analysis of Natural Gas by Gas Chromatography
ASTM D1946 Standard Practice for Analysis of Reformed Gas by Gas Chromatography
ASTM D3588 Standard Practice for Calculating Heat Value, Compressibility Factor, and Relative Density of Gaseous Fuels
ASTM E1510 Standard Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs
ASTM E355 Standard Practice for Gas Chromatography Terms and Relationships*, 2024-04-20 Update
ASTM F307 Standard Practice for Sampling Pressurized Gas for Gas Analysis
ASTM D7833-12 history
2020ASTM D7833-20 Standard Test Method for Determination of Hydrocarbons and Non-Hydrocarbon Gases in Gaseous Mixtures by Gas Chromatography
2014ASTM D7833-14 Standard Test Method for Determination of Hydrocarbons and Non-Hydrocarbon Gases in Gaseous Mixtures by Gas Chromatography
2012ASTM D7833-12 Standard Test Method for Determination of Hydrocarbons and Non-Hydrocarbon Gases in Gaseous Mixtures by Gas Chromatography