ASTM D4165-06(2012)
Standard Test Method for Cyanogen Chloride in Waterthinsp;
- Standard No.
- ASTM D4165-06(2012)
- Release Date
- 2006
- Published By
- American Society for Testing and Materials (ASTM)
- Status
- Replace By
- ASTM D4165-06(2020)e1
- Latest
- ASTM D4165-06(2020)e1
- Scope
The presence of cyanogen chloride in chlorinated sanitary and industrial effluents and therefore receiving waters is of concern because of its toxicity to aquatic life.
This test method provides an analytical procedure for measuring cyanogen chloride in water.
This test method is applicable for clean metal finishing and chlorinated sanitary and industrial effluents, and also can be used to establish process control of cyanide destruction by chlorination in waste water treatment facilities.
1.1 This test method covers the determination of cyanogen chloride in water. Cyanogen chloride is normally present only at very low concentrations; it is a very labile and sparsely soluble gaseous compound. Water samples may contain cyanogen chloride after the chlorination of waste waters containing cyanide or thiocyanate compounds.
1.2 Cyanogen chloride is unstable. A quick test using a spot plate or comparator as soon as the sample is collected may be the best test, reducing the loss of cyanogen chloride during the time lapse between sampling and analysis. (See Fig. 1 for a typical decay curve for cyanogen chloride in a solution.)
1.3 This test method has been used successfully with reagent water. The analyst is responsible for determining whether the test method is applicable to the water matrix being tested. Reference is made to Test Method D of Test Methods D2036 which is based on similar chemical reactions and has been evaluated by collaborative testing in this matrix.
1.4 The lower limit of detectability is 0.005 mg CN −/L.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Note 1 and Note 2 and Section 9.
FIG. 1 Cyanogen Chloride Stability
ASTM D4165-06(2012) Referenced Document
- ASTM D1129 Standard Terminology Relating to Water
- ASTM D1193 Standard Specification for Reagent Water
- ASTM D2036 Standard Test Methods for Cyanides in Water
- ASTM D3370 Standard Practices for Sampling Water from Closed Conduits
- ASTM D3856 Standard Guide for Good Laboratory Practices in Laboratories Engaged in Sampling and Analysis of Water
- ASTM D4210 Standard Practice for Intralaboratory Quality Control Procedures and a Discussion on Reporting Low-Level Data
- ASTM D5789 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Organic Constituents
- ASTM D5847 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
- ASTM E275 Standard Practice for Describing and Measuring Performance of Ultraviolet, Visible, and Near-Infrared Spectrophotometers
- ASTM E60 Standard Practice for Analysis of Metals, Ores, and Related Materials by Molecular Absorption Spectrometry
ASTM D4165-06(2012) history
- 2020 ASTM D4165-06(2020)e1 Standard Test Method for Cyanogen Chloride in Water
- 2006 ASTM D4165-06(2012) Standard Test Method for Cyanogen Chloride in Waterthinsp;
- 2006 ASTM D4165-06 Standard Test Method for Cyanogen Chloride in Water
- 2000 ASTM D4165-00 Standard Test Method for Cyanogen Chloride in Water
