ASTM D512-12
Standard Test Methods for Chloride Ion In Water

Standard No.
ASTM D512-12
Release Date
2012
Published By
American Society for Testing and Materials (ASTM)
Status
Replace By
ASTM D512-23
Latest
ASTM D512-23
Scope

Chloride ion is under regulation in waste water, and must, therefore, be measured accurately. It is highly detrimental to high-pressure boiler systems and to stainless steel, so monitoring is essential for prevention of damage. Chloride analysis is widely used as a tool for estimating the cycles of concentration, such as in cooling tower applications. Processing waters and pickling solutions used in the food processing industries also require dependable methods of analysis for chloride.

1.1 These test methods cover the determination of chloride ion in water, wastewater (Test Method C only), and brines. The following three test methods are included:

Sections

Test Method A (Mercurimetric Titration)7 to14
Test Method B (Silver Nitrate Titration)15 to 21
Test Method C (Ion-Selective Electrode Method)22 to 29

1.2 Test Methods A, B, and C were validated under Practice D2777 77, and only Test Method B conforms also to Practice D2777 86. Refer to Sections 14, 21, and 29 for further information.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see 26.1.1.

1.5 A former colorimetric test method was discontinued. Refer to Appendix X1 for historical information.

ASTM D512-12 Referenced Document

  • ASTM D1066 Standard Practice for Sampling Steam
  • ASTM D1129 Standard Terminology Relating to Water
  • ASTM D1193 Standard Specification for Reagent Water
  • ASTM D2777 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
  • ASTM D3370 Standard Practices for Sampling Water from Closed Conduits
  • ASTM D4127 Standard Terminology Used with Ion-Selective Electrodes
  • ASTM D5810 Standard Guide for Spiking into Aqueous Samples 
  • ASTM D5847 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
  • ASTM E200 Standard Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis

ASTM D512-12 history

  • 2023 ASTM D512-23 Standard Test Methods for Chloride Ion In Water
  • 2012 ASTM D512-12 Standard Test Methods for Chloride Ion In Water
  • 2010 ASTM D512-10 Standard Test Methods for Chloride Ion In Water
  • 2004 ASTM D512-04 Standard Test Methods for Chloride Ion In Water
  • 1999 ASTM D512-89(1999) Standard Test Methods for Chloride Ion In Water
Standard Test Methods for Chloride Ion In Water



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