This guideline describes a procedure for the determination of mass concentration of gaseous ammonia in ambient air. An accumulating diffusive sampler is used for sampling because of the marginal ammonia concentration in ambient air. The measurement procedure for ammonia in ambient air described in this guideline is applicable in the mass concentratin range of 1 ?g/m3 to 150 ?g/m3 (as monthly average). Depending on measurement task and sampling type, the determination of hourly average to monthly average is also possible at higher concentrations when the sampling duration is shortened.
VDI 3869 Blatt 4-2012 Referenced Document
DIN 1304-1:1994 Letter symbols for physical quantities; symbols for general use
DIN 1310:1984 Composition of (gaseous, liquid and solid) mixtures; concepts, symbols
DIN 38406-5:1983 German standard methods for the examination of water, waste water and sludge; cations (group E); determination of ammonia-nitrogen (E 5)
DIN 5491:1970 Mass transfer (diffusion and transport of matter); basic concepts, quantities, symbols, dimensionless parameters
DIN EN 13528-3:2004 Ambient air quality - Diffusive samplers for the determination of concentrations of gases and vapours - Part 3: Guide to selection, use and maintenance; German version EN 13528-3:2003
DIN EN ISO 11732:2005 Water quality - Determination of ammonium nitrogen - Method by flow analysis (CFA and FIA) and spectrometric detection (ISO 11732:2005); German version EN ISO 11732:2005
DIN EN ISO 14911:1999 Water quality - Determination of dissolved Li<(hoch)+>, Na<(hoch)+>, NH<(Index)4><(hoch)+>, K<(hoch)+>, Mn<(hoch)2+>, Ca<(hoch)2+>, Mg<(hoch)2+>, Sr<(hoch)2+> and Ba<(hoch)2+> using ion chromatography - Method for water and waste water (ISO 14911:1998); G
DIN EN ISO 20988:2007 Air quality - Guidelines for estimating measurement uncertainty (ISO 20988:2007); English version of DIN EN ISO 20988:2007-09
VDI 1000-2010 VDI Guideline Work - Principles and procedures
VDI 3497 Blatt 3-1988 Determination of particulate anions in ambient air; analysis of chloride, nitrate, and sulfate by ion chromatography using suppressor technique after aerosol sampling on PTFE-filters
VDI 3497 Blatt 4-1991 Determination of particulate anions in ambient air; analysis of chloride, nitrate, and sulphate by ion chromatography using single-column-technique after aerosol sampling on PTFE-filters
VDI 3869 Blatt 3-2010 Measurement of ammonia in ambient air - Sampling with diffusion separators (denuders) - Photometric or ion chromatographic analysis
VDI 3869 Blatt 4-2012 history
2012VDI 3869 Blatt 4-2012 Measurement of ammonia in ambient air - Sampling with diffusive samplers - Photometric or ion chromatographic analysis
2010VDI 3869 Blatt 4-2010 Messen von Ammoniak in der Aussenluft - Probenahme mit Passivsammlern - Fotometrische oder ionenchromatografische Analyse
1996VDI 3869 Blatt 4-1996 Measurement of acids and bases in ambient air - Measurement of ammonia; sampling in diffusion separators coated with citric acid - Determination by indophenol method