ASTM D4663-10
Standard Test Method for Polyurethane Raw Materials Determination of Hydrolyzable Chlorine of Isocyanates

Standard No.
ASTM D4663-10
Release Date
2010
Published By
American Society for Testing and Materials (ASTM)
Status
Replace By
ASTM D4663-15
Latest
ASTM D4663-20
Scope

This test method can be used for research or for quality control to characterize toluene diisocyanates. Hydrolyzable chlorine correlates with performance in some polyurethane systems.

1.1 This test method determines the hydrolyzable chlorine content of toluene-2,4-diisocyanate, toluene-2,6-diisocyanate, or mixtures of the two. It is acceptable to apply this test method to other isocyanates of suitable solubility. (See Note 1.) The main sources of hydrolyzable chlorine in the isocyanates are carbamoyl chloride and dissolved phosgene. Both of these compounds react with alcohols and water, forming ureas, carbamates, carbon dioxide, and hydrochloric acid. (See Note 2.)

1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Note 18212;It is possible that this test method is applicable crude polymeric isocyanates. However, the precision with crude polymeric isocyanates has not been established.

Note 28212;There is no known ISO equivalent to this standard.

ASTM D4663-10 history

  • 2020 ASTM D4663-20 Standard Test Method for Polyurethane Raw Materials: Determination of Hydrolyzable Chlorine of Isocyanates
  • 2015 ASTM D4663-15 Standard Test Method for Polyurethane Raw Materials: Determination of Hydrolyzable Chlorine of Isocyanates
  • 2010 ASTM D4663-10 Standard Test Method for Polyurethane Raw Materials Determination of Hydrolyzable Chlorine of Isocyanates
  • 1998 ASTM D4663-98(2004) Standard Test Method for Polyurethane Raw Materials Determination of Hydrolyzable Chlorine of Isocyanates
  • 1998 ASTM D4663-98 Standard Test Method for Polyurethane Raw Materials Determination of Hydrolyzable Chlorine of Isocyanates
Standard Test Method for Polyurethane Raw Materials  Determination of Hydrolyzable Chlorine of Isocyanates



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