ASTM C871-08a
Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions

Standard No.
ASTM C871-08a
Release Date
2008
Published By
American Society for Testing and Materials (ASTM)
Status
Replace By
ASTM C871-08ae1
Latest
ASTM C871-18(2023)
Scope

Research has demonstrated that in addition to the halide ion chloride; fluoride ions, when deposited and concentrated on the surface of austenitic stainless steel, can contribute to external stress corrosion cracking (ESCC) in the absence of inhibiting ions. Two widely used insulation specifications that are specific to ESCC allow the use of the same Test Methods C 692 and C 871 for evaluation of insulation materials. Both specifications require fluoride ions to be included with chloride ions when evaluating the extractable ions.

Chlorides (and fluorides) can be constituents of the insulating material or of the environment, or both. Moisture in the insulation or from the environment can cause chlorides (and fluorides) to migrate through the insulation and concentrate at the hot stainless steel surface.

The presence of sodium and silicate ions in the insulation has been found to inhibit external stress corrosion cracking caused by chloride (and fluoride) ions, whether such ions come from the insulation itself or from external sources. Furthermore, if the ratio of sodium and silicate ions to chloride (and fluoride) ions is in a certain proportion in the insulation, external stress corrosion cracking as a result of the presence of chloride (and fluoride) in the insulation will be prevented or at least mitigated (see also Specification C 795).

1.1 These test methods cover laboratory procedures for the determination of water-leachable chloride, fluoride, silicate, and sodium ions in thermal insulation materials in the parts per million range.

1.2 Selection of one of the test methods listed for each of the ionic determinations required shall be made on the basis of laboratory capability and availability of the required equipment and appropriateness to the concentration of the ion in the extraction solution.

1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ASTM C871-08a Referenced Document

  • ASTM C168 Standard Terminology Relating to Thermal Insulation
  • ASTM C692 Standard Test Method for Evaluating the Influence of Thermal Insulations on External Stress Corrosion Cracking Tendency of Austenitic Stainless Steel
  • ASTM C795 Standard Specification for Thermal Insulation for Use in Contact with Austenitic Stainless Steel
  • ASTM D1428 Methods of Test for Sodium and Potassium in Water and Water-Formed Deposits by Flame Photometry

ASTM C871-08a history

  • 2023 ASTM C871-18(2023) Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2018 ASTM C871-18 Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2011 ASTM C871-11e1 Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2011 ASTM C871-11 Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2008 ASTM C871-08ae2 Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2008 ASTM C871-08ae1 Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2008 ASTM C871-08a Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2008 ASTM C871-08 Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 2004 ASTM C871-04 Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
  • 1995 ASTM C871-95(2000) Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions
Standard Test Methods for  Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions



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