The scope of this technical report is to present the background considerations which led to this
compilation of potentials of the aqueous saturated calomel electrode compared to the
cyclovoltametric data for a glassy carbon electrode in various solvent media. A tabulation of
working potentials of this electrode pair in various solvent media is presented. A comparison of
the cyclovoltametric scans for the ferricinium/ferrocene and deamethyl derivatized
ferricinium/ferrocene redox couple system is presented and important features are discussed.
IEC TR 62456:2007 history
2007IEC TR 62456:2007 An electrochemical reference system for use in different solvent media - The decamethylated ferricinium/ferrocence redox couple