This part of ISO 6145 specifies a method for the continuous production of calibration gas mixtures, containing two or more components, from pure gases or other gas mixtures by use of commercially available thermal mass-flow controllers. By adjustment of set-points on flow controllers to pre-determined values, it is possible to change the composition of the gas mixture rapidly and in a continuously variable manner. By selection of appropriate combinations of thermal mass-flow controllers and with use of pure gases, the volume fraction of the component of interest in the complementary gas can be varied by a factor of 1 000. The relative expanded uncertainty of measurement, U, obtained by multiplying the relative combined standard uncertainty by a coverage factor, k = 2, is not greater than 2 %.
If pre-mixed gases are used instead of pure gases, mole fractions below 10 can be obtained. The measurement of mass flow is not absolute and the flow controller requires independent calibration.
The merits of the method are that a large quantity of the gas mixture can be prepared on a continuous basis and that multi-component mixtures can be prepared as readily as binary mixtures if the appropriate number of thermal mass-flow controllers is utilized.
Gas blending systems, based upon thermal mass-flow controllers, and some including the facility of computerization and automatic control, are commercially available.
ISO 6145-7:2001 history
2018ISO 6145-7:2018 Gas analysis — Preparation of calibration gas mixtures using dynamic volumetric methods — Part 7: Thermal mass-flow controllers
2009ISO 6145-7:2009 Gas analysis - Preparation of calibration gas mixtures using dynamic volumetric methods - Part 7: Thermal mass-flow controllers
2001ISO 6145-7:2001 Gas analysis - Preparation of calibration gas mixtures using dynamic volumetric methods - Part 7: Thermal mass-flow controllers