This International Standard specifies a method for the extraction, with aqua regia, of trace elements from soils and similar materials, prepared according to ISO 11464, and containing less than about 20% (m/m) organic carbon according to ISO 10694. Ma-terials containing more than about 20 % (m/m) organic carbon will require treatment with additional nitric acid (see note 8). The resulting solution is suitable for the determination of trace elements using appropriate atomic spectrometric techniques. With high solute concentrations in extract solutions, spectral inter-ferences and background enhancement should be expected.
NOTE 1 Aqua regia will not totally dissolve most soils and similar materials, and the efficiency of extraction for par-ticular elements differs from element to element. Such ef-ficiency might also differ for the same element in different matrices. Users of this International Standard should carry out a programme of analysis using reference materials to assure themselves that the method given here is appropri-ate for their needs. Elements extractable in aqua regia can-not, therefore, be decribed as "totals"; conversely they cannot be regarded as the "bio-available" fraction, as the extraction procedure is too vigorous to represent any bio-logical process.
BS 7755-3.9:1995 history
1995BS 7755-3.9:1995 Soil quality. Chemical methods. Extraction of trace elements soluble in aqua regia