1.1 This test method covers the determination of the butanol content of butanol for blending with gasoline by gas chromatography.
1.2 Butanol is determined from 95 % to 99.9 % by mass, acetone is determined from
0.02 % to
1.5 % by mass, ethanol is determined from
0.02 % to
1.5 % by mass, and methanol is determined from
0.02 % to
1.5 % by mass. Equations used to convert these individual components from mass percent to volume percent are provided. This test method has not been evaluated for use with the butanol isomer 2-methyl-2-propanol.
1.3 This test method identifies and quantifies acetone, ethanol, and methanol, but does not purport to identify all individual components that may be present in butanol for gasoline blending.
1.4 Water cannot be determined by this test method and shall be measured by a procedure such as Test Method D1364 and the result used to correct the chromatographic values.
1.5 This test method is inappropriate for impurities that boil at temperatures higher than 225 °C or for impurities that cause poor or no response in a flame ionization detector, such as water.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D7875-20 Referenced Document
ASTM D1298 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D1364 Standard Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)
ASTM D4052 Standard Test Method for Density and Relative Density of Liquids by Digital Density Meter
ASTM D4057 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D4307 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
ASTM D4626 Standard Practice for Calculation of Gas Chromatographic Response Factors
ASTM D4806 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
ASTM D6299 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance*, 2023-07-01 Update
ASTM D6300 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D7862 Standard Specification for Butanol for Blending with Gasoline for Use as Automotive Spark-Ignition Engine Fuel*, 2024-04-22 Update
ASTM E1064 Standard Test Method for Water in Organic Liquids by Coulometric Karl Fischer Titration*, 2024-01-01 Update
ASTM E355 Standard Practice for Gas Chromatography Terms and Relationships*, 2024-04-22 Update
ASTM E594 Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography
ASTM D7875-20 history
2020ASTM D7875-20 Standard Test Method for Determination of Butanol and Acetone Content of Butanol for Blending with Gasoline by Gas Chromatography
2014ASTM D7875-14 Standard Test Method for Determination of Butanol and Acetone Content of Butanol for Blending with Gasoline by Gas Chromatography