ASTM D5501-20
Standard Test Method for Determination of Ethanol and Methanol Content in Fuels Containing Greater than 20 % Ethanol by Gas Chromatography

Standard No.

ASTM D5501-20

Release Date

2020

Published By

American Society for Testing and Materials (ASTM)

Latest

ASTM D5501-20

Scope

1.1 This test method covers the determination of the ethanol content of hydrocarbon blends containing greater than 20 % ethanol. This method is applicable to denatured fuel ethanol, ethanol fuel blends, and mid-level ethanol blends. 1.1.1 Ethanol is determined from 20 % by mass to 100 % by mass and methanol is determined from 0.01 % by mass to 0.6 % by mass. Equations used to convert these individual alcohols from percent by mass to percent by volume are provided. NOTE 1—Fuels containing less than 20 % ethanol may be quantified using Test Method D5599, and less than 12 % ethanol may be quantified using Test Method D4815. 1.2 This test method does not purport to identify all individual components common to ethanol production or those components that make up the denaturant or hydrocarbon constituent of the fuel. 1.3 Water cannot be determined by this test method and shall be measured by a procedure such as Test Method D7923, E203, or E1064 and the result used to correct the concentrations determined by this method. 1.4 This test method is inappropriate for impurities that boil at temperatures higher than 225 °C or for impurities that cause poor or no response in a flame ionization detector, such as water. 1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are provided for information purposes only. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D5501-20 Referenced Document

• ASTM D1298 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
• ASTM D1364 Standard Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)
• ASTM D4052 Standard Test Method for Density and Relative Density of Liquids by Digital Density Meter
• ASTM D4057 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
• ASTM D4175 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants*， 2023-07-01 Update
• ASTM D4307 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
• ASTM D4626 Standard Practice for Calculation of Gas Chromatographic Response Factors
• ASTM D4806 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
• ASTM D4815 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C₁ to C₄ Alcohols in Gasoline by Gas Chromatography
• ASTM D5599 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection*， 2022-04-01 Update
• ASTM D5798 Standard Specification for Fuel Ethanol (Ed75-Ed85) for Automotive Spark-Ignition Engines
• ASTM D6299 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance*， 2023-07-01 Update
• ASTM D6792 Standard Practice for Quality Management Systems in Petroleum Products, Liquid Fuels, and Lubricants Testing Laboratories*， 2023-11-01 Update
• ASTM D7923 Standard Test Method for Water in Ethanol and Hydrocarbon Blends by Karl Fischer Titration
• ASTM E1064 Standard Test Method for Water in Organic Liquids by Coulometric Karl Fischer Titration*， 2024-01-01 Update
• ASTM E1510 Standard Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs*， 2021-04-01 Update
• ASTM E203 Standard Test Method for Water Using Volumetric Karl Fischer Titration
• ASTM E3237 Standard Specification for Undenatured Ethanol from Biomass for Use in Industrial Applications
• ASTM E355 Standard Practice for Gas Chromatography Terms and Relationships*， 2024-04-22 Update
• ASTM E594 Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography

ASTM D5501-20 history

• 2020 ASTM D5501-20 Standard Test Method for Determination of Ethanol and Methanol Content in Fuels Containing Greater than 20 % Ethanol by Gas Chromatography
• 2012 ASTM D5501-12(2016) Standard Test Method for Determination of Ethanol and Methanol Content in Fuels Containing Greater than 20% Ethanol by Gas Chromatography
• 2012 ASTM D5501-12e1 Standard Test Method for Determination of Ethanol and Methanol Content in Fuels Containing Greater than 20% Ethanol by Gas Chromatography
• 2012 ASTM D5501-12 Standard Test Method for Determination of Ethanol and Methanol Content in Fuels Containing Greater than 20% Ethanol by Gas Chromatography
• 2009 ASTM D5501-09 Standard Test Method for Determination of Ethanol Content of Denatured Fuel Ethanol by Gas Chromatography
• 2004 ASTM D5501-04 Standard Test Method for Determination of Ethanol Content of Denatured Fuel Ethanol by Gas Chromatography
• 1994 ASTM D5501-94(1998)e1 Standard Test Method for Determination of Ethanol Content of Denatured Fuel Ethanol by Gas Chromatography