ASTM D4047-13
Standard Test Method for Phosphorus in Lubricating Oils and Additives by Quinoline Phosphomolybdate Method

Standard No.

ASTM D4047-13

Release Date

2013

Published By

American Society for Testing and Materials (ASTM)

Status

Be replaced

Replace By

ASTM D4047-18

Latest

ASTM D4047-18

Scope

4.1 Knowledge of the phosphorus content, and thus the phosphorus-containing additives, in a lubricating oil or additive can be used to predict performance characteristics.

1.1 This test method covers the determination of 0.005 to 10.0 mass % phosphorus in unused lubricating oil and additive concentrates. There is no reason to doubt its applicability to filtered, used lubricating oils, but no systematic study of this application has been made.

1.2 The test method is applicable to samples containing any of the phosphorus compounds in normal use.

Note 1—This test method extends the scope of the previous version of IP 149 and replaces IP 148 and the previous version of IP 149 as a referee method.

1.3 This test method is free from most interferences because the high insolubility of the quinoline phosphomolybdate precipitate leads to constant composition and freedom from most adsorbed or occluded impurities, especially from cations which would otherwise interfere in the subsequent titration of the precipitate.

1.4 Barium, calcium, magnesium, zinc, iron, aluminum, alkali salts, citric acid and citrates, chromium up to 18 times the phosphorus content, and titanium up to 3.5 times do not interfere with the test method.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 6.9.

ASTM D4047-13 Referenced Document

• ASTM D1193 Standard Specification for Reagent Water
• ASTM D6299 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance*， 2023-07-01 Update

ASTM D4047-13 history

• 2018 ASTM D4047-18 Standard Test Method for Phosphorus in Lubricating Oils and Additives by Quinoline Phosphomolybdate Method
• 2013 ASTM D4047-13 Standard Test Method for Phosphorus in Lubricating Oils and Additives by Quinoline Phosphomolybdate Method
• 2000 ASTM D4047-00(2011) Standard Test Method for Phosphorus in Lubricating Oils and Additives by Quinoline Phosphomolybdate Method
• 2000 ASTM D4047-00(2005) Standard Test Method for Phosphorus in Lubricating Oils and Additives by Quinoline Phosphomolybdate Method
• 2000 ASTM D4047-00 Standard Test Method for Phosphorus in Lubricating Oils and Additives by Quinoline Phoshomolybdate Method