1.1 This guide is intended to serve as a reference for laboratories wishing to perform 99 Tc analyses in soil. Several options are given for selection of a tracer and for the method of extracting the Tc from the soil matrix. Separation of Tc from the sample matrix is performed using an extraction chromatography resin. Options are then given for the determination of the 99 Tc activity in the original sample. It is up to the user to determine which options are appropriate for use, and to generate acceptance data to support the chosen procedure.
1.2 Due to the various extraction methods available, various tracers used, variable detection methods used, and lack of certified reference materials for 99 Tc in soil, there is insufficient data to support a single method written as a standard method.
1.3 The values stated in SI units are to be regarded as standard, except where the non-SI unit of molar, M, is used for the concentration of chemicals and reagents. The values given in parentheses after SI units are provided for information only and are not considered standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM C1387-23 Referenced Document
ASTM C859 Standard Terminology Relating to Nuclear Materials
ASTM C998 Standard Practice for Sampling Surface Soil for Radionuclides
ASTM C999 Standard Practice for Soil Sample Preparation for the Determination of Radionuclides
ASTM D1193 Standard Specification for Reagent Water
ASTM D7168 Standard Test Method for 99Tc in Water by Solid Phase Extraction Disk
ASTM D8026 Standard Practice for Determination of Tc-99 in Water by Inductively Coupled Plasma Mass Spectrometry (ICP-MS)
ASTM E11 Standard Specification for Wire Cloth and Sieves for Testing Purposes
ASTM C1387-23 history
2023ASTM C1387-23 Standard Guide for the Determination of Technetium-99 in Soil
2014ASTM C1387-14 Standard Guide for the Determination of Technetium-99 in Soil
2008ASTM C1387-08 Standard Guide for the Determination of Technetium-99 in Soil
2003ASTM C1387-03 Standard Guide for the Determination of Technetium-99 in Soil
1998ASTM C1387-98 Standard Guide for Determination of Technetium-99 in Soil