1.1 Test Method A—Proton Nuclear Magnetic Resonance Spectroscopy (1 H NMR) measures polymerized ethylene oxide (EO) content of ethylene oxide (EO) propylene oxide (PO) polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols initiated from glycols of EO or PO containing EO percentages >5. For triols initiated with glycerol (glycerin) and trimethylolpropane, an uncorrected EO value is obtained since both initiators have protons that contribute to the EO measurement.
1.2 Test Method B—Carbon-13 Nuclear Magnetic Resonance Spectroscopy (13 C NMR) measures the polymerized EO content of EO-PO polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols and triols made from the commonly used initiators and containing EO percentages >5.
1.3 The values stated in SI units are to be regarded as standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. NOTE 1—There is no known ISO equivalent to this standard.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D4875-18 Referenced Document
ASTM D883 Standard Terminology Relating to Plastics
ASTM E2977 Standard Practice for Measuring and Reporting Performance of Fourier-Transform Nuclear Magnetic Resonance (FT-NMR) Spectrometers for Liquid Samples
ASTM E691 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM D4875-18 history
2024ASTM D4875-24 Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
2018ASTM D4875-18 Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
2011ASTM D4875-11 Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
2005ASTM D4875-05 Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
1999ASTM D4875-99 Standard Test Methods of Polyurethane Raw Materials Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols