1.1 This guide covers information for using Combustion, Inert Gas Fusion and Hot Extraction instruments to determine the mass fraction of the non-metallic elements Carbon, Sulfur, Nitrogen, Oxygen and Hydrogen in metals, ores and related materials.
1.2 This guide does not specify all the operating conditions because of the differences among different manufacturer’s instruments. Laboratories should follow instructions provided by the manufacturer of the instrument.
1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 The information in this guide is contained in the sections indicated as follows: Sections Carbon/Sulfur by Combustion/Infrared Detection 14 – 19 Nitrogen/Oxygen by Inert Gas Fusion/Thermal Conductivity and Infrared Detection 20 – 25 Hydrogen by Inert Gas Fusion Instrumental Measurement and Hot Extraction/Various Detection Cell Technology 26 – 31
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM E3346-22 Referenced Document
ASTM E1329 Standard Practice for Verification and Use of Control Charts in Spectrochemical Analysis*, 2024-04-21 Update
ASTM E135 Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E1806 Standard Practice for Sampling Steel and Iron for Determination of Chemical Composition
ASTM E2857 Standard Guide for Validating Analytical Methods
ASTM E2972 Standard Guide for Production, Testing, and Value Assignment of In-House Reference Materials for Metals, Ores, and Other Related Materials
ASTM E50 Standard Practice for Apparatus, Reagents, and safety Precautions for Chemical Analysis of Metals
ASTM E55 Standard Practice for Sampling Wrought Nonferrous Metals and Alloys for Determination of Chemical Composition
ASTM E88 Standard Practice for Sampling Nonferrous Metals and Alloys in Cast Form for Determination of Chemical Composition
ASTM E882 Standard Guide for Accountability and Quality Control in the Chemical Analysis Laboratory
ASTM G93 Standard Practice for Cleaning Methods and Cleanliness Levels for Material and Equipment Used in Oxygen-Enriched Environments
ASTM E3346-22 history
2022ASTM E3346-22 Standard Guide for Combustion, Inert Gas Fusion and Hot Extraction Instruments for use in Analyzing Metals, Ores, and Related Materials