1.1 This guide covers the selection, establishment, and application of monitoring systems for carbon and carbon compounds by on-line, automatic analysis, and recording or otherwise signaling of output data. The system chosen will depend on the purpose for which it is intended (for example, regulatory compliance, process monitoring, or to alert the user to adverse trends) and on the type of water to be monitored (low purity or high purity, with or without suspended particulates, purgeable organics, or inorganic carbon). If it is to be used for regulatory compliance, the test method published or referenced in the regulations should be used in conjunction with this guide and other ASTM test methods. This guide covers carbon concentrations of
0.05 µg/L to 50 000 mg/L. Low end sensitivity and quantitative results may vary among instruments. This guide covers the on-line measurement techniques listed in Table 1. Additional laboratory test methods are available: Test Methods D4129, D4839, D5904, D6317, and D7573.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D1193 Standard Specification for Reagent Water
ASTM D2777 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
ASTM D3370 Standard Practices for Sampling Water from Closed Conduits
ASTM D3694 Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
ASTM D3864 Standard Guide for Continual On-Line Monitoring Systems for Water Analysis
ASTM D4129 Standard Test Method for Total and Organic Carbon in Water by High Temperature Oxidation and by Coulometric Detection
ASTM D4453 Standard Practice for Handling of Ultra-Pure Water Samples
ASTM D4839 Standard Test Method for Total Carbon and Organic Carbon in Water by Ultraviolet, or Persulfate Oxidation, or Both, and Infrared Detection
ASTM D5904 Standard Test Method for Total Carbon, Inorganic Carbon, and Organic Carbon in Water by Ultraviolet, Persulfate Oxidation, and Membrane Conductivity Detection
ASTM D5997 Standard Test Method for On-Line Monitoring of Total Carbon, Inorganic Carbon in Water by Ultraviolet, Persulfate Oxidation, and Membrane Conductivity Detection
ASTM D6317 Standard Test Method for Low Level Determination of Total Carbon, Inorganic Carbon and Organic Carbon in Water by Ultraviolet, Persulfate Oxidation, and Membrane Conductivity Detection
ASTM D7573 Standard Test Method for Total Carbon and Organic Carbon in Water by High Temperature Catalytic Combustion and Infrared Detection
ASTM D5173-15(2023) history
2023ASTM D5173-15(2023) Standard Guide for On-Line Monitoring of Total Organic Carbon in Water by Oxidation and Detection of Resulting Carbon Dioxide
2015ASTM D5173-15 Standard Guide for On-Line Monitoring of Total Organic Carbon in Water by Oxidation and Detection of Resulting Carbon Dioxide
1997ASTM D5173-97(2007) Standard Test Method for On-Line Monitoring of Carbon Compounds in Water by Chemical Oxidation, by UV Light Oxidation, by Both, or by High Temperature Combustion Followed by Gas Phase NDIR or by Electrolytic Conductivity
2001ASTM D5173-97(2001) Standard Test Method for On-Line Monitoring of Carbon Compounds in Water by Chemical Oxidation, by UV Light Oxidation, by Both or by High Temperature Combustion Followed by Gas Phase NDIR or by Electr