1.1 These test methods are used to measure the isocyanate content of aromatic isocyanates used as polyurethane raw materials.
1.1.1 Test Method A—Unheated toluene-dibutylamine determines the toluene diisocyanate content, the amine equivalent and the isocyanate content of refined toluene-2,4-diisocyanate and toluene-2,6-diisocyanate, or mixtures of the two. Other isomers, if present, will be included in the determination. This test method is also applicable to other isocyanates of suitable reactivity and solubility.
1.1.2 Test Method B—Heated toluene-dibutylamine determines the amine equivalent and the isocyanate content of crude or modified isocyanates derived from toluene diisocyanate, methylene di-(4-phenylisocyanate) and polymeric (methylene phenylisocyanate).
1.1.3 Test Method C—Unheated trichlorobenzene-toluenedibutylamine determines the amine equivalent and the isocyanate content of crude or modified isocyanates derived from toluene diisocyanate, methylene-di-(4-phenylisocyanate) and polymeric (methylene phenylisocyanate).
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. NOTE 1—Method C of this test method is equivalent to Method B of ISO 14896.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D5155-19 Referenced Document
ASTM D1193 Standard Specification for Reagent Water
ASTM D883 Standard Terminology Relating to Plastics*, 2024-02-01 Update
ASTM E180 Standard Practice for Determining the Precision of ASTM Methods for Analysis and Testing of Industrial and Specialty Chemicals
ASTM E2935 Standard Practice for Evaluating Equivalence of Two Testing Processes*, 2021-06-01 Update
ASTM E456 Standard Terminology for Relating to Quality and Statistics
ASTM E691 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ISO 14896 Plastics - Polyurethane raw materials - Determination of isocyanate content
ASTM D5155-19 history
2019ASTM D5155-19 Standard Test Methods for Polyurethane Raw Materials: Determination of the Isocyanate Content of Aromatic Isocyanates
2014ASTM D5155-14e1 Standard Test Methods for Polyurethane Raw Materials: Determination of the Isocyanate Content of Aromatic Isocyanates
2014ASTM D5155-14 Standard Test Methods for Polyurethane Raw Materials: Determination of the Isocyanate Content of Aromatic Isocyanates
2010ASTM D5155-10 Standard Test Methods for Polyurethane Raw Materials Determination of the Isocyanate Content of Aromatic Isocyanates
2007ASTM D5155-07 Standard Test Methods for Polyurethane Raw Materials Determination of the Isocyanate Content of Aromatic Isocyanates
2001ASTM D5155-01 Standard Test Methods for Polyurethane Raw Materials Determination of the Isocyanate Content of Aromatic Isocyanates
1996ASTM D5155-96 Standard Test Methods for Polyurethane Raw Materials Determination of the Isocyanate Content of Aromatic Isocyanates